Chemical & Petrochemical Processing
Application Specification

Ball Valves for Chemical & Petrochemical Processing

Ball valves, globe valves, PTFE-lined and diaphragm valves in Hastelloy C-276, Alloy 20, SS 316L, and lined designs for acids, solvents, and aggressive chemical process service.

Which ball valves are used for chemical & petrochemical processing?

Chemical and petrochemical plants handle the broadest range of aggressive fluids: concentrated sulphuric acid, hydrochloric acid, nitric acid, caustic soda, chlorine, bromine, organic solvents, and speciality chemicals. Valve material selection requires matching both the chemical resistance of body and trim materials and the operating pressure and temperature to ensure safe, leak-free operation. NACE MR0103 compliance is required for refinery-adjacent chemical plants handling H₂S-bearing streams.

Ball Valve (Hastelloy / Alloy 20 / SS 316L)

Chemical-resistant block valve for acids, chlorinated compounds, and aggressive organic solvents in high-pressure reactor service

MaterialsA494 CW6MC (Hastelloy C-276 cast), A351 CN7M (Alloy 20), A351 CF3M (SS 316L), Duplex F51
Pressure ClassClass 150 / 300 / 600 / 900
StandardsAPI 6D, ASME B16.34, API 607, API 608

PTFE-Lined Ball Valve

Hydrochloric acid, sulphuric acid, and oxidising chemical service - PTFE lining provides chemical resistance at lower cost than solid exotic alloys

MaterialsCS or DI body with full PTFE lining (PTFE ball, PTFE seats, PTFE stem sleeve)
Pressure ClassPN 10 / PN 16 / PN 25
StandardsASME B16.34, ISO 9001, EN 12266

Critical Requirements

  • Chemical compatibility verification for every service - pH, temperature, concentration, and mixed chemical effects
  • Fugitive emission control: ISO 15848-1 Class A/B for benzene, chlorinated solvents, and toxic chemical services
  • PTFE-lined or solid alloy construction for halide (Cl, Br, F) acid service - SS 316 is inadequate for concentrated HCl
  • NACE MR0103 for refinery-adjacent chemical plants with H₂S exposure (stricter hardness limits than MR0175)
  • IBR certification for steam-traced piping and reactor steam-heated jackets
  • Antistatic design and ATEX actuators for flammable solvent services

Service Challenges

  • Concentrated sulphuric acid (H₂SO₄ >93%) - use cast iron, Hastelloy B-3, or PTFE-lined; SS 316 passivates at high concentration but fails at dilute concentrations
  • Hydrochloric acid (HCl) - one of the most aggressive chemicals; Hastelloy C-276 or PTFE lining required for all concentrations
  • Nitric acid (HNO₃) - SS 316L is suitable for dilute service; for concentrated, Hastelloy C-276 or borosilicate-lined
  • Chlorine gas (Cl₂, dry) - Hastelloy C-276 or nickel alloy; wet chlorine (Cl₂ dissolved in water) requires titanium or PVDF lining
  • Caustic soda (NaOH, 50%) at elevated temperature - SS 316 can suffer SCC; nickel-lined or Alloy 400 recommended above 65°C

Vajra Ball Valves

High-performance ball valves for reliable shut-off and control in various industrial applications.

See the full Ball Valves range

Other valves for chemical & petrochemical processing

Ball Valves for other applications

Reviewed by Product Engineering, Vajra Industrial SolutionsDiscipline: Valve Product EngineeringLast reviewed: 20 June 2026

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