HomeService by FluidChlorine (Cl₂)

hazardousCl₂CAS 7782-50-5

Valves for Chlorine (Cl₂) Service

Chlorine is a powerful oxidiser and highly toxic gas (IDLH: 10 ppm). Dry chlorine gas is handled in carbon steel; wet or moist chlorine attacks virtually all metals. Valve selection follows Chlorine Institute Pamphlet 6 recommendations.

Pressure Range

Up to 25 bar for liquid Cl₂

Temperature

-34°C (liquid) to 120°C (gas)

Industries

Water treatment, PVC / chlorinated chemicals, Bleach production

INDICATIVE ONLY - Reference DisclaimerChlorine service is Category M lethal/toxic. All engineering specifications must be reviewed and approved by a qualified process safety engineer. Valve selection must comply with Chlorine Institute Pamphlet 6. Vajra Industrial Solutions accepts no liability for material selection decisions based on this guide.

What valves are used for Chlorine (Cl₂) service?

Carbon steel gate/globe valve (dry Cl₂) are recommended for Chlorine (Cl₂) service: Chlorine Institute Pamphlet 6 approved for dry service.

Key Properties - Chlorine (Cl₂)

  • Dry Cl₂ (gas or liquid): carbon steel is acceptable
  • Wet Cl₂ (>50 ppm moisture): attacks carbon steel rapidly
  • IDLH (immediately dangerous to life): 10 ppm
  • Strong oxidiser - PVC and PTFE preferred for lining
  • Chlorine reacts violently with hydrocarbons and ammonia

Vajra Industrial Solutions manufactures and supplies valves for Chlorine (Cl₂) service — including carbon steel gate/globe valve (dry cl₂) — in corrosion-appropriate materials selected for the operating conditions described here, with full material and test documentation.

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Material Compatibility - Chlorine (Cl₂)

Ratings are indicative. Actual compatibility depends on concentration, temperature, velocity, and presence of contaminants. Always consult corrosion tables or a materials engineer.

MaterialRatingNotes
Carbon Steel (dry service)GoodAcceptable for dry chlorine gas and liquid. Passivates with iron chloride layer.
SS 316LFairWet chlorine - not recommended due to Cl-SCC. Dry service - acceptable.
Hastelloy C-276ExcellentBest all-round choice for both wet and dry service.
PTFEExcellentCompletely inert. Preferred for seats, seals, and lining.
PVC / FRPGoodFor wet chlorine at low pressure.
Monel 400GoodGood for dry chlorine; not for wet.
Copper alloysNot RecommendedAttacked rapidly.
TitaniumPoorRisk of titanium-chlorine fire at elevated temperature.

Recommended Valves

Carbon steel gate/globe valve (dry Cl₂)

Chlorine Institute Pamphlet 6 approved for dry service

Full selection guide

Hastelloy C-276 ball valve (wet Cl₂)

Best corrosion resistance for wet chlorine service

Full selection guide

PTFE-seated ball valve

PTFE seats are inert to all chlorine service conditions

Full selection guide

Forged globe valve - extended bonnet

Slow-opening design prevents surge in toxic gas service

Full selection guide

Valves to Avoid

Valves with copper alloy trim or seals

Titanium-bodied valves in hot service

Rubber-seated valves (chlorine attacks most elastomers)

Valves not rated for toxic/lethal service per ASME B31.3 Category M

Special Considerations

Category M service per ASME B31.3 - zero leakage to atmosphere required
All maintenance requires SCBA and full PPE
Emergency isolation valve (EIV) with remote actuator required
Valve actuators must be pneumatic (spring-return fail-close) for toxic service
No organic lubricants on valve internals - use chlorinated or PTFE-based lubricant only

Applicable Standards

Chlorine Institute Pamphlet 6ASME B31.3 Category M (toxic service)ISO 15848 Class A (fugitive emissions)NFPA 72 (detection)

Shop Valves for Chlorine (Cl₂) Service

Other Fluid Services

Part of the Vajra Fluid Service Library

Chlorine (Cl₂) Service — Procurement & Specification

Typical Applications

Water treatmentPVC / chlorinated chemicalsBleach productionPulp & paperDisinfection

Available Standards

Chlorine Institute Pamphlet 6ASME B31.3 Category M (toxic service)ISO 15848 Class A (fugitive emissions)NFPA 72 (detection)

Material Options

Carbon Steel (dry service)Hastelloy C-276PTFEPVC / FRPMonel 400

Documentation Available

  • -EN 10204 3.1 Material Test Certificates (heat traceable)
  • -API 598 hydrostatic shell & seat test reports
  • -Dimensional inspection reports
  • -Full Manufacturing Data Record (MDR) / data book on request
View documentation package

Inspection Options

  • -In-house QC inspection on every order
  • -Third-party inspection (SGS / Bureau Veritas / TÜV / DNV) coordination
  • -Witness and hold points accommodated on request
View inspection & testing

Order Quantities

Flexible — from single critical-spare valves to full project lots.

Export

Worldwide export with complete documentation (COO, EUR.1, packing lists) to 20+ countries.

Custom Engineering

Built to your specification — materials, trim, pressure class and special service (NACE, fire-safe, IBR, cryogenic).

Delivery Support

Dispatch from Vadodara, Gujarat with documented lead times and priority handling for urgent requirements.

Engineering references

Reviewed by Process Engineering, Vajra Industrial SolutionsDiscipline: Process & Fluid Service EngineeringLast reviewed: 20 June 2026

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