HomeService by FluidSulphuric Acid (H₂SO₄)

corrosiveH₂SO₄CAS 7664-93-9

Valves for Sulphuric Acid (H₂SO₄) Service

Sulphuric acid is one of the most widely used industrial chemicals. Corrosivity varies dramatically with concentration: dilute acid (<50%) is highly aggressive to most metals; concentrated acid (>93%) passivates carbon steel but attacks stainless steels.

Pressure Range

0.5–25 bar (7–360 psi) - process dependent

Temperature

Ambient to 80°C typical; up to 200°C in some processes

Industries

Chemical, Fertiliser, Mining (acid leach)

INDICATIVE ONLY - Reference DisclaimerMaterial compatibility data is indicative only based on published corrosion tables. Actual service life depends on concentration, temperature, flow velocity, and presence of contaminants. Always conduct coupon testing or consult a corrosion engineer. Vajra Industrial Solutions accepts no liability for material selection decisions based on this guide.

What valves are used for Sulphuric Acid (H₂SO₄) service?

PTFE-lined ball valve are recommended for Sulphuric Acid (H₂SO₄) service: Full bore, zero dead-legs, PTFE lining handles all concentrations.

Key Properties - Sulphuric Acid (H₂SO₄)

  • Highly corrosive at dilute concentrations (<50%)
  • Carbon steel passivates above 78% concentration
  • Stainless steel 316 acceptable up to ~20% at low temperature
  • Generates heat on dilution - thermal shock risk
  • Strong oxidiser at high concentrations

Vajra Industrial Solutions manufactures and supplies valves for Sulphuric Acid (H₂SO₄) service — including ptfe-lined ball valve — in corrosion-appropriate materials selected for the operating conditions described here, with full material and test documentation.

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Material Compatibility - Sulphuric Acid (H₂SO₄)

Ratings are indicative. Actual compatibility depends on concentration, temperature, velocity, and presence of contaminants. Always consult corrosion tables or a materials engineer.

MaterialRatingNotes
Carbon Steel (WCB/A105)GoodOnly for >93% concentrated acid at ambient temperature. Not for dilute acid.
SS 316LFairUp to ~20% at <25°C. Not recommended above 20% or elevated temperature.
Hastelloy C-276ExcellentExcellent across all concentrations. Industry standard for dilute H₂SO₄.
PTFE-linedExcellentPTFE is excellent across all concentrations and temperatures up to 200°C.
FRP / PVDF-linedGoodPVDF and FRP good for <80% concentrations.
Ductile IronPoorNot recommended for any concentration.
Bronze / BrassNot RecommendedSeverely attacked. Never use copper alloys.
Duplex 2205FairLimited to dilute, cold service only. Verify with corrosion data.

Recommended Valves

PTFE-lined ball valve

Full bore, zero dead-legs, PTFE lining handles all concentrations

Full selection guide

Hastelloy C-276 ball valve

Alloy wetted parts for dilute acid service

Full selection guide

PTFE-lined butterfly valve

Cost-effective for large bore, low-pressure dilute acid

Full selection guide

Diaphragm valve (PTFE/EPDM)

No stem packing contact with fluid - ideal for leakage-sensitive service

Full selection guide

Alloy-body globe valve

Throttling service in corrosive acid streams

Full selection guide

Valves to Avoid

Bronze or brass-bodied valves

Standard SS 316 for concentrated acid above 20%

Rubber-lined valves (except EPDM in specific concentrations)

Valves with copper alloy trim

Special Considerations

Always design for double containment or secondary containment
Emergency shower and eyewash must be immediately accessible
Full-bore valves preferred to minimise turbulence and localised attack
Dilution point design must prevent acid-in-water splashback
ATEX rating required where sulphur vapours present

Applicable Standards

ASME B16.34ISO 15761NACE MR0103 (where H₂S present)API 607 (fire safe)

Shop Valves for Sulphuric Acid (H₂SO₄) Service

Other Fluid Services

Part of the Vajra Fluid Service Library

Sulphuric Acid (H₂SO₄) Service — Procurement & Specification

Typical Applications

ChemicalFertiliserMining (acid leach)Battery manufacturingSteel picklingRefinery (alkylation)

Available Standards

ASME B16.34ISO 15761NACE MR0103 (where H₂S present)API 607 (fire safe)

Material Options

Carbon Steel (WCB/A105)Hastelloy C-276PTFE-linedFRP / PVDF-lined

Documentation Available

  • -EN 10204 3.1 Material Test Certificates (heat traceable)
  • -API 598 hydrostatic shell & seat test reports
  • -Dimensional inspection reports
  • -Full Manufacturing Data Record (MDR) / data book on request
View documentation package

Inspection Options

  • -In-house QC inspection on every order
  • -Third-party inspection (SGS / Bureau Veritas / TÜV / DNV) coordination
  • -Witness and hold points accommodated on request
View inspection & testing

Order Quantities

Flexible — from single critical-spare valves to full project lots.

Export

Worldwide export with complete documentation (COO, EUR.1, packing lists) to 20+ countries.

Custom Engineering

Built to your specification — materials, trim, pressure class and special service (NACE, fire-safe, IBR, cryogenic).

Delivery Support

Dispatch from Vadodara, Gujarat with documented lead times and priority handling for urgent requirements.

Engineering references

Reviewed by Process Engineering, Vajra Industrial SolutionsDiscipline: Process & Fluid Service EngineeringLast reviewed: 20 June 2026

Connected Engineering

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