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Valve Material Reference

ASTM B164 / UNS N04400 (Monel 400) Valve

Monel 400

Monel 400 (UNS N04400) is a nickel-copper alloy with exceptional resistance to hydrofluoric acid (HF), fluorine, seawater, and reducing environments.

Form

Both

Max Temp

+480°C (+900°F)

Min Temp

−196°C (−321°F)

Category

Nickel Alloy

Chemical Composition — ASTM B164 / UNS N04400 (Monel 400)

Ni ≥ 63%, Cu 28–34%, Fe ≤ 2.5%, Mn ≤ 2.0%, C ≤ 0.30%, Si ≤ 0.50%, S ≤ 0.024%.

Temperature Range

−196°C to +480°C (−321°F to +900°F)

Maximum Temperature

+480°C (+900°F)

Minimum Temperature

−196°C (−321°F)

Equivalent Grades — ASTM B164 / UNS N04400 (Monel 400)

StandardEquivalent Grade
UNSN04400
ASTMB164 (bar), B127 (plate), B564 (forged)
ENNiCu30Fe / 2.4360

Suitable Services

Hydrofluoric acid (HF) alkylation units in oil refineries

Seawater injection, produced water treatment, ballast water

Chlorine gas service at low concentrations

Caustic soda manufacturing and concentration

Hydrogen sulphide (H₂S) and salt solutions

Marine hardware and offshore pipeline valves

Not Suitable For

Concentrated HNO₃ (nitric acid) — severe corrosion

Concentrated H₂SO₄ (sulphuric acid) above 80% concentration

Oxidising salts at elevated temperature

Valve Body Applications

HF alkylation unit valves (entire valve wetted path in Monel 400)

Seawater injection valve bodies for offshore platforms

Caustic soda (NaOH) concentration plant valves

Fluorocarbon and fluorine gas handling valves

Trim Applications

Ball valve balls — solid Monel 400 or Monel overlay

Gate and globe valve seats — Monel 400 bar

Stem — Monel K500 (age-hardened variant) for higher strength

Typical Valve Types in ASTM B164 / UNS N04400 (Monel 400)

Ball valves: HF alkylation service, Class 150–600

Gate valves: seawater injection, Class 150–600

Globe valves: caustic service, control service

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Technical Reference

Industry Applications · 10 min read

How to Specify Industrial Valves for Chemical Service: A Complete Guide

Chemical plants handle some of the most aggressive fluids in any industry — strong acids, chlorinated solvents, caustic solutions, oxidising agents, and toxic gases. Specifying the wrong valve body material, seat, or seal material can lead to catastrophic corrosion, product contamination, or unsafe failure. This guide covers every variable in chemical valve specification.

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